An estimated 83.1% of over-50s within the capital had obtained each doses of vaccine by 20 June.
All different areas are above 90%, with south-west England reporting the best proportion at 95.0%.
The figures have been revealed by NHS England, and are available forward of a summit assembly in London tomorrow to debate how one can increase vaccine take-up in London.
The summit might be attended by the London mayor, Sadiq Khan, the vaccines minister, Nadhim Zahawi, the regional medical director for London, Vin Diwakar, and others.
Based on a PA evaluation, the highest 19 native authority areas in England with the bottom proportion of adults aged 50 and over to be absolutely vaccinated are all in London.
The bottom proportion is for Westminster (64.3%), adopted by the Metropolis of London (66.3%), Camden (68.9%) and Kensington & Chelsea (70.9%).
The areas of London estimated to have the best proportion of over-50s absolutely vaccinated are Bromley (91.7%), Richmond upon Thames (91.6%) and Sutton (90.4%).